锂二氧化锰 MSDS.pdf

Page 1 of 4 Lithium Manganese Dioxide Batteries October, 2010 ©2010 Energizer PRODUCT SAFETY DATA SHEET PRODUCT NAME: Energizer Battery Type No.: Volts: 3.0 TRADE NAMES: Energizer Lithium Manganese Dioxide Batteries Approximate Weight: 0.6 – 40 g. CHEMICAL SYSTEM: Lithium Manganese Dioxide Designed for Recharge: No SECTION 1- MANUFACTURER INFORMATION Manufactured for Energizer Battery Manufacturing, Inc. Telephone Number for Information: 25225 Detroit Rd. Westlake, OH 44145 800-383-7323 (USA / CANADA) Date Prepared: October, 2010 SECTION 2 – HAZARDS IDENTIFICATION Under normal conditions of use, the battery is hermetically sealed. Ingestion: Swallowing a battery can be harmful. Inhalation: Contents of an open battery can cause respiratory irritation. Skin Contact: Contents of an open battery can cause skin irritation. Eye Contact: Contents of an open battery can cause severe irritation. SECTION 3 - INGREDIENTS IMPORTANT NOTE: The battery should not be opened or burned. Exposure to the ingredients contained within or their combustion products could be harmful. MATERIAL OR INGREDIENT PEL (OSHA) TLV (ACGIH) %/wt. Carbon Black (CAS# 1333-86-4) 3.5 mg/m3 TWA 3.5 mg/m3 TWA 0-1 1,2-Dimethoxyethane (CAS# 110-71-4) None established None established 0-6 1,3-Dioxolane (CAS# 646-06-0) None established None established 0-8 Graphite (CAS# 7782-42-5) 15 mg/m3 TWA (total dust) 5 mg/m3 TWA (respirable fraction) 2 mg/m3 TWA (respirable fraction) 0-3 Lithium or Lithium Alloy (CAS# 7439-93-2) None established None established 1-6 Lithium Trifluoromethanesulfonate (CAS# 33454-82-9) None established None established 0-3 Lithium Trifluoromethanesulfonimide (CAS# 90076-65-6) None established None established 0-3 Manganese Dioxide (CAS# 1313-13-9) 5 mg/m3 Ceiling (as Mn) 0.2 mg/m3 TWA (as Mn) 12-42 Propylene Carbonate (CAS# 108-32-7) None established None established 0-8 Non-Hazardous Components: Steel (iron CAS# 7439-89-6) Plastic and Other None established None established None established None established 20 Balance Page 2 of 4 Lithium Manganese Dioxide Batteries October, 2010 ©2010 Energizer SECTION 4 – FIRST AID MEASURES Ingestion: Do not induce vomiting or give food or drink. Seek medical attention immediately. CALL NATIONAL BATTERY INGESTION HOTLINE for advice and follow-up (202-625-3333) collect day or night. Inhalation: Provide fresh air and seek medical attention. Skin Contact: Remove contaminated clothing and wash skin with soap and water. Eye Contact: Immediately flush eyes thoroughly with water for at least 15 minutes, lifting upper and lower lids, until no evidence of the chemical remains. Seek medical attention. Note: Carbon black is listed as a possible carcinogen by International Agency for Research on Cancer (IARC). SECTION 5- FIRE FIGHTING MEASURES In case of fire where lithium batteries are present, flood area with water or smother with a Class D fire extinguishant appropriate for lithium metal, such as Lith-X. Water may not extinguish burning batteries but will cool the adjacent batteries and control the spread of fire. Burning batteries will burn themselves out. Virtually all fires involving lithium batteries can be controlled by flooding with water. However, the contents of the battery will react with water and form hydrogen gas. In a confined space, hydrogen gas can form an explosive mixture. In this situation, smothering agents are recommended. A smothering agent will extinguish burning lithium batteries. Emergency Responders should wear self-contained breathing apparatus. Burning lithium manganese dioxide batteries produce toxic and corrosive lithium hydroxide fumes. SECTION 6 - ACCIDENTAL RELEASE MEASURES To cleanup leaking batteries: Ventilation Requirements: Room ventilation may be required in areas where there are open or leaking batteries. Respiratory Protection: Avoid exposure to electrolyte fumes from open or leaking batteries. Eye Protection: Wear safety glasses with side shields if handling an open or leaking battery. Gloves: Use neoprene or natural rubber gloves if handling an open or leaking battery. Battery materials should be collected in a leak-proof container. SECTION 7 - HANDLING AND STORAGE Storage: Store in a cool, well ventilated area. Elevated temperatures can result in shortened battery life. In locations that handle large quantities of lithium batteries, such as warehouses, lithium batteries should be isolated from unnecessary combustibles. Mechanical Containment: If potting or sealing the battery in an airtight or watertight container is required, consult your Energizer Battery Manufacturing, Inc. representative for precautionary suggestions. Do not obstruct safety release vents on batteries. Encapsulation of batteries will not allow cell venting and can cause high pressure rupture. Handling: Accidental short circuit for a few seconds will not seriously affect the battery. Prolonged short circuit will cause the battery to lose energy, 。