8347编号附录Ⅵ 物质的标准摩尔生成焓、标准摩尔生成吉.pdf

附录 物质的标准摩尔生成焓、标准摩尔生成吉附录 物质的标准摩尔生成焓、标准摩尔生成吉 布斯函数、标准摩尔熵和摩尔热容(100kPa)布斯函数、标准摩尔熵和摩尔热容(100kPa) (1)单质和无机物(1)单质和无机物 fHm (298.15 K) (298.15 K) fGm (298.15 K) (298.15 K) Sm (298.1 5K) (298.1 5K) Cp,m (298.15K ) (298.15K )物质物质 kJmol-1 -1 kJmol-1 -1 JK-1mol-1 -1 JK-1mol-1 -1 Ag(s)0042.71225.48 Ag2CO3(s)-506.14-437.09167.36 Ag2O(s)-30.56-10.82121.7165.57 Al(s)0028.31524.35 Al(g)313.80273.2164.553 Al2O3--1669.8-2213.160.98679.0 Al2(SO4)3(s ) -3434.98-3728.53239.3259.4 Br2(g)111.88482.396175.021 Br2(g)30.713.109245.45535.99 Br2(l)00152.335.6 C(g)718.384672.942158.101 C(金刚石)1.8962.8662.4396.07 C(石墨)005.6948.66 CO(g)-110.525-137.285198.01629.142 CO2(g)-393.511-394.38213.7637.120 Ca(s)0041.6326.27 CaC2(s)-62.8-67.870.262.34 CaCO3(方解 石) -1206.87-1128.7092.881.83 CaCl2(s)-795.0-750.2113.872.63 CaO(s)-635.6-604.239.748.53 Ca(OH)2(s)-986.5-896.8976.184.5 CaSO4(硬石 膏) -1432.68-1320.24106.797.65 Cl-(aq)-167.456-131.16855.10 Cl2(g)00222.94833.9 Cu(s)0033.3224.47 CuO(s)-155.2-127.143.5144.4 Cu2O--166.69-146.33100.869.8 F2(g)00203.531.46 Fe-0027.1525.23 FeCO3(s)-747.68-673.8492.882.13 FeO(s)-266.52-244.354.051.1 Fe2O3(s)-822.1-741.090.0104.6 Fe3O4(s)-117.1-1014.1146.4143.42 H(g)217.94203.122114.72420.80 H2(g)00130.69528.83 D2(g)00144.88429.20 HBr(g)-36.24-53.22198.6029.12 HBr(aq)-120.92-102.8080.71 HCl(g)-92.311-95.265186.78629.12 HCl(aq)-167.44-131.1755.10 H2CO3(aq)-698.7-623.37191.2 Hl(g)-25.94-1.32206.4229.12 H2O(g)-241.825-228.577188.82333.571 H2O(l)-285.838-237.14269.94075.296 H2O(s)-291.850(-234.03）(39.4） H2O2(l)-187.61-118.04102.2682.29 H2S(g)-20.146-33.040205.7533.97 H2SO4(l)-811.35(-866.4）156.85137.57 H2SO4(aq)-811.32 HSO4(aq)-885.75-752.99126.86 l2(g)00116.755.97 I2(g)62.24219.34260.6036.87 N2(g)00191.59829.12 NH3(g)-46.19-16.603192.6135.65 NO(g)89.86090.37210.30929.861 NO2(g)33.8551.86240.5737.90 N2O(g)81.55103.62220.1038.70 N2O4(g)9.66098.39304.4279.0 N2O5(g)2.51110.5342.4108.0 O(g)247.521230.095161.06321.93 O2(g)00205.13829.37 O3(g)142.3163.45237.738.15 OH-(aq)-229.940-157.297-10.539 S(单斜)0.290.09632.5523.64 S(斜方)0031.922.60 (g)124.9476.08227.7632.55 S(g)222.80182.27167.825 SO2(g)-296.90-300.37248.6439.79 SO3(g)-395.18-370.40256.3450.70 SO42- (aq)-907.51-741.9017.2 (2)有机化合物(2)有机化合物 fHm (298.15K) (298.15K) fGm (298.15K) (298.15K) Sm (298.15K ) (298.15K ) Cp,m (298.15 K) (298.15 K)物质物质 kJmol-1 -1 kJmol-1 -1 JK-1mol-1 -1 JK-1mol-1 -1 烃类烃类 CH4(g),甲烷-74.84750.827186.3035.715 C2H2(g),乙炔226.748209.200200.92843.928 C2H4(g),乙烯52.28368.157219.5643.56 C2H6(g),乙烷-84.667-32.821229.6052.650 C3H6(g),丙烯20.41462.783267.0563.89 C3H6(g),丙烷-103.847-23.391270.0273.51 C4H6(g),1,3-丁二烯110.16150.74278.8579.54 C4H8(g),1-丁烯-0.1371.60305.7185.65 C4H8(g),顺-2-丁烯-6.9965.96300.9478.91 C4H8(g),反-2-丁烯-11.1763.07296.5987.82 C4H8(g),2-甲基两烯-16.9058.17293.7089.12 C4H10(g),正丁烷-126.15-17.02310.2397.45 C4H10(g),异丁烷-134.52-20.79294.7596.82 C6H6(g),苯82.927129.723269.3181.67 C6H6(l),苯49.028124.597172.35135.77 C6H12(g),环己烷-123.1431.92298.51106.27 C6H14(g),正己烷-167.19-0.09388.85143.09 C6H14(l),正己烷-198.82-4.08295.89194.93 C6H5CH3(g),甲苯49.999122.388319.86103.76 C6H5CH3(l),甲苯11.995114.299219.58157.11 C6H4(CH2）(g)邻二甲苯18.995122.207352.86133.26 C6H4（CH3）2(l),邻二甲苯-24.439110.495246.48187.9 C6H4（CH3）2(g),间二甲苯17.238118.977357.80127.57 C6H（CH3）2（l),间二甲苯-25.418107.817252.17183.3 C6H4（CH3）2(g),对二甲苯17.949121.266352.53126.86 C6H4（CH3）2(l),对二甲苯-24.426110.244247.36183.7 含氧化合物含氧化合物 HCOH(g),甲醛-115.90-110.0220.235.36 HCOOH(g),甲酸-362.63-335.69251.154.4 HCOOH(l),甲酸-409.20-345.9128.9599.04 CH3OH(g),甲醇-201.17-161.83237.849.4 CH3OH(l),甲醇-238.57-166.15126.881.6 CH2COH(g),乙醛-166.36-133.67265.862.8 CH3COOH(l),乙酸-487.0-392.4159.8123.4 CH3COOH(g),乙酸-436.4-381.5293.472.4 C2H5OH(l),乙醇-277.63-174.36160.7111.46 C2HOH(g),乙醇-235.31-168.54282.171.1 CH3COCH3（l),丙酮-248.283-155.33200.0124.73 CH3COCH3(g),丙酮-216.69-152.2296.0075.3 C2H5OC2H5(l),乙醚-273.2-116.47253.1 CH3COOC2H5(l),乙酸乙酯-463.2-315.3259 C6H5COOH（s),苯甲酸-384.55-245.5170.7155.2 卤代烃卤代烃 CH3Cl(g),氯甲烷-82.0-58.6234.2940.79 CH2Cl2(g),二氯甲烷-88-59270.6251.38 CHCl3（l),氯仿-131.8-71.4202.9116.3 CHCl3(g),氯仿-100-67296.4865.81 CCl4(l),四氯化碳-139.3-68.5214.43131.75 CCl4(g),甲氯化碳-106.7-64.0309.4185.51 C6H5Cl(l),氯苯116.3-198.2197.5145.6 含 氮 化 合 物含 氮 化 合 物 NH（CH3）2(g),二甲胺-27.659.1273.269.37 C5H5N(l),吡啶78.87159.9179.1 C6H5NH2(l),苯胺35.31153.35191.6199.6 C6H5NO2，(l)硝基苯15.90146.36244.3 本附录数据主要取自 Handbook of Chemistry and Physics, 70 th Ed., 1990; Editor John A.Dean,Langes Handbook of Chemistry, 1967。