过氧化氢MSDS.doc

过氧化氢 HS ;2847000000过氧化氢化学式为 H2O2，俗称双氧水，外观为无色透明液体，是一种 强氧化剂，适用于伤口消毒及环境、食品消毒中文名： 过氧化氢外文名： Hydrogen peroxide别名： 双氧水化学式： H2O2相对分子质量： 34.01化学品类别： 无机物--过氧化物管制类型： 过氧化氢(*)（易制爆）储存： 用瓶口有微孔的塑料瓶装阴凉保存编辑本段 基本信息球棍模型 [1]中文名称:过氧化氢中文同义词:双氧水;氢过氧化物;二氧化二氢; 过氧化氢(85%);双氧水(85%);50%双氧水;HTP英文名称:Hydrogen peroxide英文同义词:PERONE;PERHYDROL;PERHYDROL(R);PERDROGEN;PEROXIDE;SUPEROXOL;60%solution;60%solutioninwater;Albone 35毒害物质数据:7722-84-1(Hazardous Substances Data)职业标准:TWA 1.4 毫克/立方米; STEL 4.2 毫克/立方米 [2]编辑本段 物理性质水溶液为无色透明液体，溶于水、醇、乙醚，不溶于石油醚。

[3]纯的过氧化氢是一种淡蓝色粘稠状液体 [4]纯过氧化氢是淡蓝色的粘稠液体，熔点-0.43 °C，沸点150.2 °C凝固点时固体密度为1.71g/cm3，密度随温度升高而减小它的缔合程度比 H2O 大，所以它的介电常数和沸点比水高纯过氧化氢比较稳定，若加热到153 °C 便猛烈的分解为水和氧气纯过氧化氢过氧化氢分子为椅型结构，左图为气态时的结构，右图为固态晶体时的结构过氧化氢可溶于乙醇、乙醚，不溶于苯对有机物有很强的氧化作用，一般作为氧化剂使用 [5]MSDSName: Hydrogen Peroxide 35 wt.% Solution in Water Stabilized P.A. Material Safety Data SheetSynonym: Carbamide peroxide; Hydrogen dioxide; Peroxide; Hydroperoxide; Urea peroxide; Hydrogen peroxide 100 CAS 号 7722-84-1[2]熔点（℃） -33 °C[2]沸点（℃） 108 °C[2]折射率 1.3350[2]EINECS 登录号 231-765-0[2]密度 1.13 g/mL at 20 °C[2]闪点 107°CvolumesCAS: 7722-84-1Section 1 - Chemical ProductMSDS Name:Hydrogen Peroxide 35 wt.% Solution in Water Stabilized P.A. Material Safety Data Sheet Synonym:Carbamide peroxide; Hydrogen dioxide; Peroxide; Hydroperoxide; Urea peroxide; Hydrogen peroxide 100 volumes Section 2 - COMPOSITION, INFORMATION ON INGREDIENTSCAS# Chemical Name content EINECS#7722-84-1 Hydrogen peroxide 35 231-765-0Hazard Symbols: O C Risk Phrases: 34 8 Section 3 - HAZARDS IDENTIFICATIONEMERGENCY OVERVIEWCauses burns. Contact with combustible material may cause fire.Corrosive.Light sensitive.Potential Health EffectsEye:Contact with liquid is corrosive to the eyes and causes severe burns. Contact with the eyes may cause corneal damage.Skin:Causes severe skin irritation and possible burns. May cause discoloration, erythema (redness), swelling, and the formation of papules and vesicles (blisters).Ingestion:Causes gastrointestinal irritation with nausea, vomiting and diarrhea. Causes gastrointestinal tract burns. May cause vascular collapse and damage. May cause damage to the red blood cells. May cause difficulty in swallowing, stomach distension, possible cerebral swelling and death. Ingestion may result in irritation of the esophagus, bleeding of the stomach and ulcer formation.Inhalation:Causes chemical burns to the respiratory tract. May cause ulceration of nasal tissue, insomnia, nervous tremors with numb extremities, chemical pneumonia, unconsciousness, and death. At high concentrations, respiratory effects may include acute lung damage and delayed pulmonary edema.Chronic:Prolonged or repeated skin contact may cause dermatitis. Laboratory experiments have resulted in mutagenic effects. Repeated contact may cause corneal damage.Section 4 - FIRST AID MEASURESEyes: Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes).Skin:Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.Ingestion:Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. Wash mouth out with water. Vomiting may occur spontaneously. If vomiting occurs and the victim is conscious, give water to further dilute the chemical.Inhalation:Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.Notes to Physician:Treat symptomatically and supportively. Attempts at evacuating the stomach via emesis induction or gastric lavage should be avoided. In the event of severe distension of the stomach or esophagus due to gas formation, insertion of a gastric tube may be required. To treat corneal damage, careful ophthalmologic evaluation is recommended and the possibility of local corticosteroid therapy should be considered.Section 5 - FIRE FIGHTING MEASURESGeneral Information:As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Water runoff can cause environmental damage. Dike and collect water used to fight fire. Strong oxidizer. Contact with other material may cause fire. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.Use water spray to keep fire-exposed containers cool. Substance is noncombustible. Use water with caution and in flooding amounts.Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Some oxidizers may react explosively with hydro。