2、危废管理与预处理.ppt

2024/7/27ØWaste Category & Classification￿￿废物种类和分类ØReception & Pretreatment team￿￿接收和预处理部门ØWaste storage control￿￿废物存储管理ØWaste pretreatment￿￿废物预处理2024/7/27ØChinese National standard of HW￿国家危废标准ØHW code list￿危废名录ØHW package,￿storage and tagging￿危废包装，存储和标示ØWAC system￿and￿deviation￿report WAC体系和偏差报告ØWAC list 废料接受证书列表ØSpecial￿waste￿特殊废物ØCategory based on pre-treatment￿基于预处理的分类2024/7/27HJ 2025-2012 is general standard for collection, storage, transportation of hazardous waste￿￿￿HJ 2025-2012为危废收集，存储和运输的一般标准Other￿main￿standards其它主要标准GB190￿￿￿￿￿￿￿危险货物包装标志GB5085.1~7￿￿危险废物鉴别标准GB6944￿￿￿￿￿￿危险货物分类和品名编号GB12463￿￿￿￿￿危险货物运输包装通用技术条件2024/7/272024/7/27Other￿main￿standards其它主要标准GB13392￿￿￿道路运输危险货物车辆标志GB15603￿￿￿常用化学危险品贮存通则GB15562.2￿环境保护图形标志-固体废物贮存(处置)场GB18597￿￿￿危险货物贮存污染控制标准HJ/T298￿￿￿危险废物鉴别技术规范JT617￿￿￿￿￿汽车运输危险货物规则JT618￿￿￿￿￿汽车运输、装卸危险货物作业规程2024/7/27Laws￿and￿regulations￿￿￿法律规范1.危险化学品安全管理条例(2011)2.危险化学品经营许可证管理办法(2004)3.危险废物转移联单管理办法(1999)4.废弃危险化学品污染环境防治办法(2005)5.国家危险废物名录(2008)6.道路危险货物运输管理规定(2005)GB 5085 is general rule of HW classification GB 5085是危废分类的一般准则GB 5085.1 to GB 5085.6 are detailed rules to identify category of hazardous waste GB 5085.1 到 GB 5085.6是识别危废的详细准则HW is classified as corrosive waste, toxic waste, flammable waste and reactive waste￿￿￿危废是以腐蚀性，毒性，易燃性和反应性进行分类HJ/T298 gives detailed identify method for HW HJ/T298是识别危废的详细方法2024/7/27According to Law of the People's Republic of China on the Prevention and Control of Environmental Pollution by Solid Wastes (2004 Revision), hazardous waste list is published in 1998 and updated in 2008 根据中华人民共和国固体废物污染环境防治法, 危废名录在1998年 ￿公布，并在2008年进行了更新Waste was classified according to production industry, process and waste material￿￿￿废物是根据生产行业，生产方法和原料种类进行分类HW producer must￿register their waste according to HW list￿￿￿危废产生单位必须根据危废名录登记废物2024/7/27HW package should follow HJ2025￿and GB12463￿￿危废包装必须根据HJ2025￿和 GB12463的标准Total 12 rules such as￿GB12463￿￿￿￿一共12条准则，例如GB12463￿Package must be strong enough, package material must be compatible with waste inside; package should be easy for load/unload￿￿￿包装必须足够牢固，包装材料必须和废物相适应，包装应该要易于装卸2024/7/272024/7/27Waste￿storage￿area/warehouse￿must￿follow￿GB18597,￿GBZ1￿and￿GBZ2￿￿￿危废存储区域和仓库必须依照GB18597,￿GBZ1￿和GBZ2为标准Facilities￿is￿requested￿such￿as￿communication,￿light￿and￿fire￿fighting￿￿￿通讯，照明和消防设施是必备的Alarm￿system￿and￿grounding￿is￿requested￿for￿flammable￿waste￿area￿￿￿存放易燃废物区域警报系统和接地是必备的Follow￿GB15603￿and￿laws/regulations￿￿￿遵照GB15603￿的法律规范For￿toxic￿waste,￿double￿key￿management￿must￿be￿performed￿￿￿对于毒性废物，必须执行双密钥管理It’s requested by GB 18597 that HW package must be tagged properly GB 18597规定危废包装必须要有合适的标示It is requested that specified tagging should be tagged for HW stock area/warehouse￿￿￿危废存储区域和仓库必须要有明确的标示2024/7/272024/7/27Register￿in￿EPB￿and￿identify￿with￿HW￿code￿￿￿通过危废号码进行识别并在环保局登记Waste￿tranfer￿sheet￿is￿requested￿for￿each￿delivery￿￿￿每次运输必须要有废物运输联单Logistic￿company￿is￿certificated￿with￿EPB￿￿￿运输公司必须要经过环保局(上海）认证2024/7/27Waste￿Acceptance￿Certificate￿￿￿废物接收证书（厂长确认）Waste￿reception￿check￿and￿WAC￿renewal￿￿￿废物接收检查和WAC更新Deviation￿report￿￿￿偏差报告2024/7/27SCIPSITA￿use￿WAC￿to￿identify￿waste￿which￿is￿available￿for￿treatment SCIPSITA通过WAC对废物进行识别，是否可以处理Waste￿material￿data￿sheet￿is￿requested￿for￿each￿WAC￿￿￿每一个WAC有相对应的废物信息数据表WAC￿is￿approved￿with￿plant￿manager WAC是由工厂厂长进行批准Waste￿cannot￿be￿delivered￿before￿WAC￿approval￿￿￿在WAC被批准之前不允许运输Comments￿from￿operation￿manager￿and￿plant￿manager￿are￿given￿as￿appendix￿￿￿生产经理和工厂厂长的处理意见作为附录2024/7/27Waste￿is￿checked￿after￿reception￿with￿visual￿inspection,￿quick￿test￿and￿labortory￿analysis￿￿￿废物是在接收之后通过目视，快速测试和实验室分析进行检查WAC￿is￿updated￿regularly WAC定期需要更新Waste￿reception￿quantity￿and￿analysis￿report￿is￿requested￿for￿WAC￿renewal￿￿￿在WAC更新时需要废物年度接收总量和分析报告Reception￿team￿gives￿suggestion￿of￿waste￿classification￿and￿packaging￿for￿WAC￿renewal￿￿￿在WAC更新时，接收部门对废物的分类和包装给出建议2024/7/27Deviation￿report￿is￿tool￿to￿improve￿waste￿management￿￿￿通过偏差报告改善废物的管理Deviation:￿waste￿received￿is￿different￿from￿WAC￿approved￿in￿material￿characteristics￿or￿waste￿package￿￿￿偏差：废物实际接收和WAC被批准时的数据信息或者包装方式有出入The￿difference￿could￿cause￿potential￿risk￿￿￿废物的变化可能存在潜在的风险The￿pretreatment￿and￿incineration￿control￿could￿be￿different￿accordingly￿￿￿废物的变化可能导致预处理和焚烧方式完全不同Deviation￿is￿reported￿by￿reception￿team￿￿￿偏差是由接收部门进行报告2024/7/27Deviation￿reports￿record￿is￿kept￿￿￿偏差报告记录进行存档Sales￿and￿reception￿team￿have￿regular￿meeting￿together￿for￿deviation￿analysis￿￿￿销售和接收部门定期对偏差报告进行商讨Reception￿team￿give￿suggestions￿to￿solve￿deviation￿￿￿接收部门对偏差给出建议的解决方案Sales￿work￿with￿customer￿to￿improve￿waste￿management￿after￿analysis￿￿销售部门根据解决方案和客户进行沟通以改善对废物的管理2024/7/27WAC￿list￿provides￿quick￿review/check￿for￿all￿waste￿acceptance￿certificate WAC列表提供对所有废物接收证书的快速查看Specified￿information￿can￿be￿found￿in￿WAC￿list￿including￿waste￿compounds￿and￿quantity,￿package,￿R/S￿info￿￿￿在WAC列表中可以查看详细信息包括废物主要成分，总量，包装方式 和R/S信息Special￿waste￿information￿can￿be￿found￿in￿WAC￿list￿￿￿在WAC列表中可以查看到特殊的废物信息2024/7/27Pretreatment￿is￿necessary￿to￿regroup￿waste￿￿￿通过预处理对废物重新分类Pretreatment￿should￿ensure￿safety￿and￿quality￿in￿waste￿incineration￿￿￿预处理应该确保焚烧的安全和效率Category￿of￿waste￿based￿on￿pretreatment￿helps￿reception￿and￿sales￿team￿in￿waste￿storage￿and￿transportaion￿control￿￿￿基于预处理的分类帮助接收和销售部门对废物的存储和运输进行管理2024/7/27Main￿work￿of￿RPT￿￿￿接收部门的主要职责Structure￿of￿RPT￿￿￿接收部门的组织架构Facilities￿￿￿设施2024/7/27Confirm￿waste￿delivery￿schedule￿￿￿确认废物运输安排Finish￿waste￿reception￿and￿unloading￿￿￿完成废物接收和卸料Report￿deviations￿in￿waste￿reception￿￿￿报告废物接收过程中的偏差Storage￿control￿in￿warehouse￿￿￿仓库的存储管理Work￿on￿different￿pretreatment￿work￿station￿to￿finish￿waste￿pretreatment￿￿￿在不同的预处理站台完成废物的预处理工作Ensure￿waste￿under￿control￿￿￿￿确保废物受控2024/7/27Field￿chemist:￿performs￿waste￿reception￿check,￿confirm￿waste￿information,￿give￿written￿reports￿of￿waste￿deviation,￿give￿instruction￿of￿waste￿pretreatment,￿give￿comments￿and￿instruction￿for￿direct￿burn￿control￿￿￿现场化学师：废物的接收检查，确认废物信息，对废物偏差给出书面 ￿报告，对废物的处理给出指导意见Field￿operator:￿finish￿daily￿reception￿and￿pretreatment￿work￿￿￿现场操作工：完成日常的接收和预处理工作2024/7/27Receiver:￿finish￿daily￿reception￿data￿input,￿reports￿for￿files￿deviation￿￿￿接收员：完成日常的接收信息录入，文档偏差的报告Supervisor:￿general￿work￿arrangement;￿coordinate￿with￿CS￿for￿waste￿reception￿schedule;￿work￿together￿with￿production￿team￿for￿waste￿incineration￿control;￿work￿on￿safety,￿environment￿and￿efficiency￿improvement￿￿￿主管：总体的工作安排，和客服部门协调废物接收安排，和生产部门 一起管理废物焚烧，完成安全，环境和效率提升的工作2024/7/27Drum￿store 桶装仓库Truck￿tank￿unloading￿station 槽车卸料站台Solid￿pit 固废池Pretreatment￿work￿station 预处理站台Fire￿fighting,￿Ventilation￿and￿safety￿shower消防，通风和安全喷淋Forklift叉车Exproof￿tools￿防爆工具Walkie￿Talkie 对讲机2024/7/27Have￿different￿functions￿in￿specified￿areas￿￿￿在特定的区域有不同的功能Truck￿unloading￿￿卡车卸料Weighing￿￿￿称重Temporary￿storage￿￿￿临时存放Some￿work￿stations￿￿￿一些工作站台2024/7/27To￿unload￿waste￿liquid￿in￿truck￿tank￿to￿tank￿farm￿￿￿把废液从槽车卸到罐区Waste￿liquid￿is￿classified￿according￿to￿carloric￿value￿￿￿废液通过热值进行分类Waste￿can￿be￿unloaded￿after￿laboratory￿analysis￿confirm￿￿￿在实验室分析信息确认之后进行卸料2024/7/27Bulk￿solid￿unloading￿￿￿散装固废卸料Storage￿for￿waste￿after￿unloading￿or￿crush￿￿￿在废物卸料或者破碎之后进行存储Mix￿different￿waste￿together￿￿￿混合不同的废物2024/7/27Shredder￿￿￿破碎机Solid￿pit￿unloading￿￿￿固废池卸料Pumping￿station￿for￿tank￿farm￿￿￿罐区抽泵站台Repacking￿to￿IBC￿￿￿灌装IBCRepacking￿to￿small￿container￿￿￿灌装小包装Solid￿waste￿repacking￿for￿shredding￿￿￿固废重新包装破碎2024/7/27Fire￿fighting￿shower￿￿￿消防喷淋Extinguisher￿￿￿灭火器Ventilation￿hood￿￿￿通风（拔风）罩Safety￿shower￿￿￿安全喷淋（低倍、中倍、消防水）2024/7/27For￿waste￿load/unload￿￿￿废物装卸Shredder￿feeding￿￿￿破碎机进料Transportation￿in￿plant￿￿￿厂区内的运输Rotary￿forklift￿for￿waste￿unloading￿￿￿旋转式叉车：废物卸料Rotary￿clamp￿forklift￿for￿drum￿dumping￿￿￿旋转夹叉车：桶装废料倾倒Overspeed￿alarm￿￿￿超速警报2024/7/27Normal￿tools￿is￿dangerous￿in￿warehouse￿and￿work￿station￿with￿flammable￿material￿￿￿在仓库和工作站台有易燃物质，普通工具具有危险性Exproof￿tools￿ensure￿low￿energy￿release￿in￿work,￿to￿avoid￿risk￿of￿fire/explosion￿￿￿防爆工具在工作时确保了低能量释放，避免了火灾和爆炸的风险Some￿operation￿may￿generate￿static,￿which￿is￿dangerous￿in￿case￿of￿flammable￿material￿exist￿￿￿一些操作会产生静电，一旦有易燃物质存在会有危险性Grounding￿container￿and￿equipment￿well￿can￿avoid￿fire/explosion￿risk￿caused￿by￿static￿￿￿接地容器和工具能避免因静电引起的火灾和爆炸风险2024/7/27Walkie￿talkie￿is￿widely￿used￿in￿plant￿for￿communication￿￿￿在厂区内，通过对讲机进行交流Walkie￿talkie￿in￿plant￿must￿be￿ex-proof￿for people￿may￿work￿in￿ex-proof￿area￿￿￿因为可能会在防爆区域工作，对讲机必须要是防爆的341. Internal classification of hazardous waste危废的内部分类2. Reception plan接收计划3. Reception control接收控制‒Package and Label control‒包装和标签的控制‒Packaged/bulk waste control‒包装以及散装废物的控制‒Lab waste control‒实验室废物的控制4. Storage management存储管理‒Storage regular‒存储规范‒Drumstore layout‒桶装仓库布局‒Routine check and weekly inventory‒日常巡检和每周库存统计5. Pretreatment control预处理控制6. Recycling package management包装循环使用管理7. 5S35Classification basis:分类准则GB 6944-2012 Classification and codes of hazardous goodsGB 6944-2012危险货物的分类和编码管理Existed pretreatment method现有的预处理方式36IndustrywasteLiquidInorganicWaste waterCleaning WW, oil/water emulsion, aqueous polymer emulsion, alkaliAcid　OxidationBleach, disinfectantOrganicOrganic LiquidDiluted glue, Paint, polymer cleaning solventOrganic SolventSovent, diluentNCO Liquid　Acrylate　Oxidation　PastyInert oligomerPolyol,Silicone, Ink, GreaseNCO oligomer　Glue　SolidMetal wasteflange, steel hose, gasketSludgeSludge, Slurry, filter residue, activated carbonNormalPPE, gloves, tissues　　Lab wasteSolidNormal solidPPE, gloves, tissues, empty plastic bottleGlass fragment　Empty glass bottle　LiquidGlass bottle with agent　Acid　Organic　Waste water　　Scrapped chemicals　Prepared by customer service team由客服部门安排Confirmed by RPT由接收部门确认Includes information of customer, waste and truck包括客户，废物和车辆信息Includes waste deliver time包括废物的运输时间Set maximum reception quantity based on pretreatment capacity根据预处理能力设定最大的接收量3738Suitable packages for each kind of waste￿￿￿￿￿每种废物对应合适的包装Meet with law and regulation ￿￿￿￿遵照法律规范GB 18597-2001 Standard for pollution control on hazardous waste control GB 18597-2001标准：污染控制和危废控制GB 190-2009 Packing symbols of dangerous goods GB 190-2009标准：危险货物的包装标示GB 12463-2009 General specification for transport packages of dangerous goods GB 12463-2009标准：危险货物的包装运输的一般准则Please refer pretreatment part for details.￿￿￿￿参考预处理部分查看详细信息Bigger packages are appreciated￿￿￿￿更偏好大包装Decrease operation times￿￿￿￿减少操作时间Increase pretreatment efficiency￿￿￿￿提高预处理效率More training to customer￿￿￿￿给客户进行更多的培训Meet laws and regulations￿￿￿￿遵照法律规范Ensure safe storage￿￿￿￿确保存储安全Increase work efficiency￿￿￿￿提高工作效率39Tracing and pretreatment reference￿￿￿￿追踪以及给预处理提供参考Complete and accurate￿￿￿￿准确而完整的Pretreatment method after site check if identified￿￿￿￿现场检查之后决定预处理方式40（（necessary））（（necessary））（（necessary））（（necessary））（（necessary））（（necessary））Pretreatment method￿￿￿预处理方式PIT/SHRED/SIDE DOOR固废池/破碎/边门Storage area: ￿￿￿存储区域Normal solid → north door, south door, solid repacking area一般固废→北门，南门，固废重新包装区域Hazardous waste → drum store危废→桶装仓库Packages￿￿￿￿包装Iron carton, big-opening IBC, plastic carton, 200L drum铁箱，大开口IBC，卡板箱，200L桶Big bag吨袋41Pretreatment method预处理方式PIT/SHRED/PUMP/SIDE DOOR固废池/破碎/抽泵/边门Storage area: 存储区域Drum store桶装仓库Package: 包装IBC, drumIBC，桶Inner plastic bag for pasty waste粘稠废物需内衬塑料袋42Pretreatment method￿￿￿预处理方式Unloading to tankfarm (Liquid)￿￿￿卸料到罐区（液体）Direct burn by AW,MW,IS1 (Liquid)￿￿￿通过AW,MW,IS1（液体）直接焚烧Unloading to pit￿￿￿卸料到固废池Unloading to SILO￿￿￿卸料到筒仓Packages:￿￿￿包装Truck tank (liquid)￿￿￿槽车（液体）Big bin (solid)￿￿￿污泥车（固体）Highest pretreatment efficiency￿￿￿最有效的预处理方式43Storage control￿￿￿存储控制Ensure compatibility of waste in same￿container ￿￿￿确保相容性合适Good￿mix￿￿￿混合均匀Relief￿valve￿for￿liquid￿tank￿￿￿液体储罐配备安全阀Enough￿ventilation￿for￿solid￿pit￿￿￿固废池有足够的通风Inventory￿￿￿存储清单Storage￿in￿TF￿links￿with￿PLC￿￿￿存储在罐区，通过PLC进行控制Storage￿of￿bulk￿solid￿updated￿everyday￿￿￿每天更新散装固废存储44Feature:￿￿特点Complex, toxic, small packages￿￿复杂，毒性，小包装Scrapped chemicals, high reactivity, corrosive, toxic￿￿报废化学品，高反应性，腐蚀性，毒性Chemical list before delivery￿￿￿每次运输前提供化学品清单Site check and pretreatment ASAP￿￿￿现场尽快检查和预处理45Feature￿￿￿￿特点Very regular with confirmed characteristics￿￿￿￿非常有规律High value￿￿￿￿高价值Supervised by customer or government￿￿￿￿由客户或者政府部门进行监管List before delivery￿￿￿￿运输前提供清单Provided by customer￿￿￿￿由客户提供Confirmed by SITA￿￿￿￿由SITA进行确认Site check and pretreatment ASAP￿￿￿￿现场尽快检查和预处理Special storage area under monitor￿￿￿￿有特定的监控存储区域46Feature￿￿￿特点Toxic or dangerous￿￿￿毒性和危险性Special storage area under monitor￿￿￿有特定的监控存储区域Pretreatment menu to control storage time￿￿￿通过预处理清单控制存储时间47Feature:￿￿￿特点Complex, toxic, small packages￿￿复杂，毒性，小包装Scrapped chemicals, high reactivity, corrosive, toxic￿￿报废化学品，高反应性，腐蚀性，毒性Chemical list before delivery￿￿￿每次运输前提供化学品清单Site check and pretreatment ASAP￿￿￿现场尽快检查和预处理48Fire fighting￿￿￿消防Enough fire fighting extinguisher in each area￿￿￿在每个区域配备足够的灭火器Automatic fire fighting system￿￿￿自动灭火系统Ventilation￿￿￿通风Enough ventilation￿for each storage area￿￿￿每个存储区域有足够的通风Safety shower￿￿￿安全喷淋Safety shower near work station￿￿￿在每个工作站台附近配备安全喷淋2024/7/2750Graphical signs on site 现场标示GB 15562.2-1995 Graphical signs for environmental protection solid waste storage site GB 15562.2-1995：固体废物存储区域环境保护标示GB 2894-2008 Safety signs and guideline for the use GB 2894-2008：安全标示以及使用准则Storage by classification 通过类别进行存储GB 18597-2001 Standard for pollution control on hazardous waste control GB 18597-2001：危废污染控制Internal classification: Acid, waste water, organic, special(oxidation, toxic, etc)￿￿￿内部分类：酸性，废水，有机，特殊（氧化性，毒性等）Waste with same hazardous code storage together￿￿￿相同危险代码的废物存储在同一地方Incompatibility waste separately storage 不相容的废物分开存储Enough gap between stacks and walls 堆垛和墙之间有足够的空隙Enough fire fighting way 足够的消防通道512-3 times/day 2-3次每天Complete labels and panels￿￿￿完善标示和面板Stable stacks￿￿￿堆垛稳定No leakage￿￿￿无泄漏No package deformation ￿￿￿无包装变形No incompatibility waste storage together￿￿￿无不相容废物同时存储52Weekly inventory recordings￿￿￿每周库存记录Recording analysis￿￿￿记录分析List near expired waste (1 year)￿￿￿列出即将过期废物（1年）Stock of each classification￿￿￿每种分类的库存Pretreatment plan of each classification￿￿￿每种分类的预处理计划53Treat small packages ASAP￿￿￿小包装尽快处理Lower storage, better control￿￿库存越少越好控制Pretreatment deadline for each classification￿￿￿每种分类的预处理期限3 hazardous levels (Level 1-3), different deadline each 3种危险等级（1-3级），不同的期限Pretreatment plan in stock inventory￿￿￿库存统计包含预处理计划Good internal material flow￿￿￿良好的内部资料流转very important to stock control￿￿￿对库存控制非常重要54Package recycling request and approval￿￿￿包装循环使用申请和批准Keep low storage of empty package with regular list￿￿￿通过列表保持空包装的低库存55Sort, Straighten, Shine, Standardize, Sustain￿￿整理，整顿，清扫，清洁，素养A safe, clean, pleasant working area￿￿安全，干净，舒心的工作环境Less efforts, less errors, less accidents￿￿较少的付出，更少的错误和事故A better team spirit, greater cohesion￿￿提升团队精神，团队凝聚力Personal satisfaction and pride￿￿个人满意，及自豪感56Part 3 Pretreatment预处理2024/7/27　　ElementElementReception limitReception limitIncinerate Incinerate concentrate concentrate (average)(average)Incinerate Incinerate concentrate concentrate (maximum)(maximum)Acid Acid elementelement　　F F0.30%0.30%1.00%1.00%ClCl1.88%1.88%5.00%5.00%BrBr0.03%0.03%0.10%0.10%I I0.00%0.00%0.10%0.10%S S0.44%0.44%2.00%2.00%P P0.50%0.50%0.50%0.50%Heavy Heavy elementelementHgHg50ppm50ppm1ppm1ppm3ppm3ppmCdCd50ppm50ppm1ppm1ppm5ppm5ppmTlTl50ppm50ppm　　　　∑Heavy metal∑Heavy metal1.00%1.00%2.80%2.80%•Unloading to solid pit 卸料到固废池•Shred 破碎•Solid repacking 固废重新包装•Pumping to tank farm 抽泵到罐区•Regroup to IBC 灌装IBC•Repack for side door 重新包装到边门•Direct burn 直接焚烧For waste in small size, unloading to solid pit is efficient pretreatment￿￿￿￿￿对于小尺寸的废物，卸料到固废池是很有效率的预处理方式Waste could be sludge/residue or normal industry waste￿￿￿￿￿废物可以是污泥/渣或者是一般的工业废物Waste cannot be corrosive to the material of solid pit (carbon steel)￿￿￿￿￿废物不能对固废池的材质具有腐蚀性（碳钢）Waste characteristics￿￿￿￿￿废物特点Reception check￿￿￿￿￿接收检查Mix￿￿￿￿￿混合Special waste￿￿￿￿￿特殊废物Packaging￿￿￿￿￿包装Solid waste including sludge/residue and normal industry waste can be unloaded when:固体废物包含污泥/渣或者是一般的工业废物只有符合以下条件才可以卸料：The waste is not flammable￿￿￿废物是不易燃的The waste is not acid￿￿￿废物不是酸性的Smell is under control￿￿￿气味必须能控制Unloading to solid pit waste characteristics卸料到固废池废物特点Size control to ensure the waste can be fed to top door￿￿￿通过尺寸控制确保废物能从顶门进料No reagent bottle for safety concern￿￿￿安全因素的考虑，不能有试剂瓶Flash point test to ensure no flammable material unloading￿￿￿通过闪点测试确保没有易燃物质pH test to ensure no acid unloading￿￿￿通过pH测试确保没有酸性物质Unloading to solid pit reception check卸料到固废池接收检查The waste in solid pit should be mixed well after unloading￿￿￿在卸料之后在固废池中的废料应该要充分混合For some special waste, good communication is very important to ensure safety in storage￿￿￿对于一些特殊的废物，通过沟通确保废物的存储安全是非常重要的Unloading to solid pit Mix卸料到固废池混合￿Certain waste is special for solid pit unloading在固废池卸料过程中，特定的废物特殊处理Glue￿￿￿胶水（极易燃）Toxic material￿￿￿毒性物质Smelly material￿￿￿有强烈气味的物质Waste with special element￿￿￿有特殊元素的废物Unloading to solid pit Special waste卸料到固废池特殊废物Control of special waste特殊废物的控制Quick incineration after unloading, for glue/toxic/smelly waste￿￿￿在卸料之后尽快焚烧，胶水，毒性和有强烈气味的废物Good mix for waste with special element￿￿￿含有特殊元素的废物必须充分混合Unloading to solid pit Special waste卸料到固废池特殊废物Big package is more efficient大包装更有效率Bulk￿￿￿散装Open IBC / steel bin / plastic bin￿￿￿开口IBC/污泥车/卡板箱Open drum￿￿￿开口桶Big bag￿￿￿吨袋Unloading to solid pit Packaging卸料到固废池包装For solid waste in big size, we have to crush the waste with shredder before incineration￿对于大尺寸的固废，我们必须先通过破碎机进行破碎之后才可以焚烧Video of shredder￿￿￿破碎机监控General work flow for shredder￿￿￿￿破碎机的一般工作流程Characteristics and Packaging￿￿￿特点和包装Special waste￿￿￿特殊废物Waste difficult to shred￿￿￿难于破碎的废物Shred Video破碎监控Field chemist directs waste for shred￿￿￿现场化学师选出需要破碎的废物Waste is classified in 3 types according to potential risk￿￿￿根据存在的潜在风险，废物分成3类Treat more dangerous in higher priority￿￿￿越危险的废物优先处理Shred General Workflow破碎一般工作流程Waste for shred must be能破碎的废物必须符合以下条件Not flammable￿￿￿不具有易燃性No metal blocks inside￿￿￿不包含金属块Not acid (pH<4)￿￿￿不是酸性（pH<4）Not highly reactive (react with water or air)￿￿￿不具有高反应性（和水或者空气反应）Shred Characteristics破碎特点Size smaller than 1.2*1.2*1.4(m)￿￿￿尺寸要小于1.2*1.2*1.4(m)Waste should be fixed stable with pallet￿￿￿废物必须固定在铲板上Package should be regular and in the middle of conveyor￿￿￿包装应该要符合规范并放置在传送带中间Shred Packaging破碎包装Shred Special Waste破碎特殊废物 Certain waste is special for shred以下特定废物在破碎时特殊处理•Toxic material 毒性物质•Smelly material 有强烈气味的物质•Waste with special element 含有特殊元素的废物Shred Special Waste破碎特殊废物 Good communication is necessary for special waste shred在特殊废物破碎时需要良好的沟通•For toxic or smelly material, burn it immediately 对于毒性和具有强烈气味的物质，必须立刻焚烧•Ensure good mix for waste with special element 对于含有特殊元素的废物，必须确保充分混合Shred Waste difficult to shred破碎难于破碎的废物 Some waste is very difficult to shred一些废物非常难破碎•Waste coils / other round material with high density 废线圈和其他高密度圆形材料•Flexible waste with high strength such as glass fibre 具有很强韧性的废物，例如玻璃纤维Flange metal法兰片The polymerization waste聚合的废物Toughness (fiber waste, tons of bags)具有很强韧性（纤维废物，吨袋）Packaging is not fixed, too high, too high包装没有固定，超尺寸Shred 破碎Waste with irregular package can only be shredded after repacking没有规则包装的废物只有在重新包装之后才可以进行破碎2024/7/27Waste liquid can be transferred to tank farm after analysisconfirm 在分析结果确认之后，废液才可以被输送到罐区Workflow￿￿￿工作流程Characteristics and packaging￿￿￿特点和包装Special waste￿￿￿特殊废物Pumping to tank farm抽泵到罐区Field chemist directs waste for pumping￿￿￿现场化学师选出可以进行抽泵的废物Analysis for each batch￿￿￿每批次进行取样分析Transfer to tank farm after laboratory analysis￿￿￿在实验室分析之后再输送到罐区Pumping to tank farm Workflow抽泵到罐区工作流程Not corrosive to carbon steel￿￿￿对碳钢不具有腐蚀性Compatible with water and liquid in tank farm￿￿￿和罐区的液体和水具有相容性Good fluidity￿￿￿流动性良好Waste is grouped with caloric value (LCV and MCV)￿￿￿废物通过热值进行分类（LCV和MCV）Big container is more efficient for pumping, such as IBC￿￿￿大包装在抽泵时更有效率，例如IBCPumping to tank farm Characteristics & Packaging抽泵到罐区特点和包装Good dilution to ensure element content in tank farm is under control￿￿￿通过稀释确保罐区的元素含量在范围之内Good communication for special element transfer to TF￿￿￿在含有特殊元素的废物输送到罐区时需要有良好的沟通No highly toxic waste pumping to tank farm￿￿￿具有高毒性的废物不能抽泵到罐区Pumping to tank farm Special Waste抽泵到罐区特殊废物Direct burn for waste cannot be unloaded to TF不能抽泵到罐区的废物需要直接焚烧Stations for waste liquid direct burn废液的直接焚烧站台IS1￿异氰酸酯类直接焚烧线AW￿酸性废料直接焚烧线MW￿熔融废料直接焚烧线Good fluidity or allows heating to decrease viscosity of waste￿￿具有良好的流动性或者加热之后废物的粘度减小Has solvent rinse￿￿溶剂冲洗Mainly for isocyanate waste, which reacts with water￿￿主要是处理异氰酸酯废物，这会和水反应Direct Burn IS1 station直接焚烧IS1站台Has PTFE liner, acid proof￿￿￿有聚四氟乙烯内衬，防酸Use diaphragm pump￿￿￿使用隔膜泵Has water rinse system￿￿￿水冲洗系统Widely use for corrosive liquid, includes acid liquid￿￿￿主要是处理具有腐蚀性的液体，包含酸性液体Available for smelly liquid or potential polymerize material which are compatible with water￿￿￿可以处理具有强烈气味的液体，或者是存在潜在聚合风险且和水相容 的物质Direct Burn AW station直接焚烧AW站台Require要求Must be liquid without SS; ￿￿￿必须是不含固体的液体Good fluidity￿￿￿具有良好的流动性Compatible with water￿￿￿和水相容Direct Burn AW station直接焚烧AW站台Has steam heat￿￿￿蒸汽伴热Has solvent rinse system￿￿￿溶剂冲洗系统Available for melting waste￿￿￿可以处理熔融废物Available for liquid which is not corrosive to carbon steel￿￿￿可以处理对碳钢不具有腐蚀性的液体Available for liquid which is possible to polymerize￿￿￿可以处理可能会聚合的液体Direct Burn MW station直接焚烧MW站台Require要求Liquid, no or little SS content必须是不含有固体或者是固含量低的液体Good fluidity or allows heating to decrease viscosity具有良好的流动性或者加热之后可以减小粘度Compatible with solvent和溶剂相容pH value≥4pH≥4Direct Burn MW station直接焚烧MW站台Field chemist directs waste to direct burn and prepares burning sheet￿with现场化学师选出需要直接焚烧的废物，并准备直接焚烧单，包含如下信息Caloric value (or CV range)￿￿￿热值（或者热值范围）Element content￿￿￿元素含量Other instructions￿￿￿其它说明2024/7/27Direct Burn Direct burn Sheet直接焚烧直接焚烧单Side door is available for the waste cannot be treated with othermethod边门可以处理其它方式无法处理的废物Workflow￿￿￿工作流程Special waste￿￿￿特殊废物Field chemist direct waste for repacking￿￿￿现场化学师选出需要重新包装的废物Follows general standard for normal waste￿￿￿对于普通废物遵照一般标准Handover to production team with burning sheet￿￿￿把焚烧单移交到生产部门Repacking for side door workflow重新包装到边门工作流程Highly toxic material￿￿￿高毒性物质Highly reactive material￿￿￿高反应性物质Smelly material￿￿￿具有强烈气味的物质Has high concentrate of special element￿￿￿有高浓度的特殊元素￿￿￿Repacking for side door special waste重新包装到边门特殊废物Treat toxic/reactive/smelly material ASAP￿￿￿毒性，高反应性和具有强烈气味的物质需要尽快处理Menu for waste with special element￿￿￿含有特殊元素的废物需要准备清单•Control repacking quantity in each container￿￿控制重新包装之后每个包装的总量•Burning requirement to limit ￿￿根据焚烧要求有所限制￿￿￿Repacking for side door special waste重新包装到边门特殊废物。